Phase transformations in ABO 4 type compounds under high pressure     

Osamu Fukunaga  Shinobu Yamaoka 《Physics and Chemistry of Minerals》1979,5(2):167-177

For ABO ₄ type ternary oxides, high pressure phase transformations known up to the present are reviewed, and an attempt is made to explain and predict crystal structures of their high pressure phases. When ABO ₄ type compounds are plotted based on the two variables, k=r _A /r _B and t=(r _A +r _B )/2r _O, where r _A , r _B , and r _O are the ionic radii of A and B cations and divalent oxygen, they can be classified into the major structure types. It is found empirically that a compound basically transforms to the structure type isostructural with a compound lying in a classified area with the same k and larger t values in the diagram.  相似文献   

Antarctic saline lakes—stable isotopic ratios,chemical compositions and evolution     

Osamu Matsubaya  Hitoshi Sakai  Tetsuya Torii  Harry Burton  Knowles Kerry 《Geochimica et cosmochimica acta》1979,43(1):7-25

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Under‐ice salinity and stable isotope distribution of Saroma‐ko Lagoon,Hokkaido, northern Japan     

Maki Morimoto  Kyoko Kawanobe  Osamu Abe  Takayoshi Kawai  Toshiyuki Kawamura  Kunio Shirasawa 《水文研究》2010,24(7):904-916

In winter, lakes and lagoons at high altitudes or high latitudes have interesting hydrological cycles that differ from those in other seasons or in other regions, because water surfaces are covered with ice. Hydrological balances of lakes and lagoons are complex dynamic systems, and to elucidate them, isotopic tracers of water have been used as effective tools along with observations of precipitation, evaporation, inflows, and outflows. Here, to understand hydrological processes during freezing periods in the brackish Saroma‐ko Lagoon, Hokkaido, northern Japan, we examined horizontal and vertical distributions of salinity and isotope compositions of lagoon water and ice in 2005 and 2006. Horizontal and vertical gradients of salinity and isotope compositions were observed from the river mouth to the sea channel, and factors determining these distributions were considered. The mixing of freshwater and seawater and a freezing effect were presumed to be factors in relationships between salinity and isotopes and in relationships between surface waters and ice just above the water. A simple box model for water balance was constructed based on these putative factors to reproduce the distributions of salinity and isotope compositions of surface waters and ice. An evaluation of the model revealed that this hydrological system is controlled primarily by horizontal advection of the epilimnion, freshwater influx, and the ice growth rate. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Distribution of <Emphasis Type="Italic">Nemopilema nomurai</Emphasis> in the southwestern Sea of Japan related to meandering of the Tsushima Warm Current     

Satoshi?KitajimaEmail author  Naoki?Iguchi  Naoto?Honda  Tatsuro?Watanabe  Osamu?Katoh 《Journal of Oceanography》2015,71(3):287-296

We investigated the horizontal distribution of Nemopilema nomurai medusae using a midwater trawl in the southwestern Sea of Japan from September to October of each year from 2006 to 2012. Numerous medusae of this species found in 2006, 2007, and 2009 were mainly distributed far (>40 km) from the mainland of Japan in the western part of the survey area, but were distributed in the stations closest (<25 km) to the mainland in the eastern part, particularly in 2006 and 2009. These distribution patterns were associated with the path of the second branch of the Tsushima Warm Current (TWC) that flows offshore to the west of Oki Islands and usually approaches the mainland of Japan to the east of Oki Islands. Differences in jellyfish distribution across the survey periods were related to the distribution of the second branch being associated with types, position and intensity of eddies in the eastern part of the survey area. Hence, the formations of eddies and consequent variation in the path of the TWC would be responsible for transporting medusae from offshore to near the mainland to the east of Oki Islands. Individuals with large bells accumulated in the northwestern part of the survey area, where a cyclonic eddy was present downstream of the third branch of the TWC. This variation in bell size distribution may be ascribed to differences in the physical and/or biological factors among the three branches of the TWC.  相似文献   

Determining the O/O ratio of water using a water-CO₂ equilibration method: Application to glacial-interglacial changes in O-excess from the Dome Fuji ice core, Antarctica     

Ryu Uemura  Osamu Abe 《Geochimica et cosmochimica acta》2010,74(17):4919-7445

Recent studies show that oxygen three isotope measurement (¹⁶O, ¹⁷O, and ¹⁸O) of water provides additional information for investigating the hydrological cycle and paleoclimate. For determining the ¹⁸O/¹⁶O value of water, a conventional CO₂-water equilibration method involves measurement of the ratios of CO₂ isotopologues which were equilibrated with water. However, this long-established technique was not intended to measure the ¹⁷O/¹⁶O ratio, primarily because the historic ion correction scheme does not allow for possible deviations from a fixed (and mass-dependent) relationship between ¹⁷O/¹⁶O and ¹⁸O/¹⁶O isotope ratios. Here, we propose an improved method for obtaining the ¹⁷O/¹⁶O isotope ratio of fresh water by the equilibration method and measurement of the 45/44 CO₂ ion abundance ratio. Equations which we formulated for ¹⁷O/¹⁶O measurement have two features: first, instead of absolute isotope ratio (R), all equations are formulated in δ values, measured by isotope ratio mass spectrometry. Second, we include two “assigned” δ values of water standards in the equations, because the δ¹⁸O are commonly measured against two working standards to normalize the span of the δ scale. This approach clarifies that the contribution from ¹⁷O (¹²C¹⁶O¹⁷O⁺) to the molecular ion current at mass-to-charge ratio m/z 45 signal depends not on the absolute ¹³C/¹²C ratio, but on the relative δ¹³C differences between the working standards and the sample. The pH value of water affects δ¹⁷O estimation because δ¹³C of CO₂ was changed in the water-CO₂ system. We reevaluated this effect using a set of equations, which explicitly includes CO₂ partial pressure effect on pH value. Our new estimation of pH effect is significantly smaller than previously reported value, but it does not alter the main conclusions in the previous study. The method was verified by δ¹⁷O measurements of an international standard reference water (GISP) provided by the IAEA. We applied the method to investigate ¹⁷O-excess of the ice core drilled at the Dome Fuji station, Antarctica. A total of 1320 samples from a 130 m section around Marine Isotope Stage 9.3 (∼330,000 years before present) were measured. The error of a measurement for δ¹⁷O is 0.175‰ and that of ¹⁷O-excess is 184 per meg. Although these analytical uncertainties hampered accurate estimation of the changes in ¹⁷O-excess, the averaged data indicate that ¹⁷O-excess around MIS 9.3 was higher than during the subsequent glacial period. This approach can be applied only to fresh water samples, and additional improvements will be needed to measure samples which contains significant amount of carbonate minerals.  相似文献   

Characteristics of Triassic epithermal Au mineralization at the Q prospect,Chatree mining area,Central Thailand     

Ladda Tangwattananukul  Daizo Ishiyama  Osamu Matsubaya  Toshio Mizuta  Punya Charusiri  Hinako Sato  Koichiro Sera 《Resource Geology》2014,64(2):167-181

The Chatree deposit is located in the Loei‐Phetchabun‐Nakhon Nayok volcanic belt that extends from Laos in the north through central and eastern Thailand into Cambodia. Gold‐bearing quartz veins at the Q prospect of the Chatree deposit are hosted within polymictic andesitic breccia and volcanic sedimentary breccia. The orebodies of the Chatree deposit consist of veins, veinlets and stockwork. Gold‐bearing quartz veins are composed mainly of quartz, calcite and illite with small amounts of adularia, chlorite and sulfide minerals. The gold‐bearing quartz veins were divided into five stages based on the cross‐cutting relationship and mineral assemblage. Intense gold mineralization occurred in Stages I and IV. The mineral assemblage of Stages I and IV is characterized by quartz–calcite–illite–laumontite–adularia–chlorite–sulfide minerals and electrum. Quartz textures of Stages I and IV are also characterized by microcrystalline and flamboyant textures, respectively. Coexistence of laumontite, illite and chlorite in the gold‐bearing quartz vein of Stage IV suggests that the gold‐bearing quartz veins were formed at approximately 200°C. The flamboyant and brecciated textures of the gold‐bearing quartz vein of Stage IV suggest that gold precipitated with silica minerals from a hydrothermal solution that was supersaturated by boiling. The δ¹⁸O values of quartz in Stages I to V range from +10.4 to +11.6‰ except for the δ¹⁸O value of quartz in Stage IV (+15.0‰). The increase in δ¹⁸O values of quartz at Stage IV is explained by boiling. P_H2O is estimated to be 16 bars at 200°C. The f_CO2 value is estimated to be 1 bar based on the presence of calcite in the mineral assemblage of Stage IV. The total pressure of the hydrothermal solution is approximately 20 bars at 200°C, suggesting that the gold‐bearing quartz veins of the Q prospect formed about 200 m below the paleosurface.  相似文献   

Wet and Dry Basalt Magma Evolution at Torishima Volcano, Izu Bonin Arc, Japan: the Possible Role of Phengite in the Downgoing Slab   总被引：1，自引：0，他引：1  

Tamura  Y.; Tani  K.; Chang  Q.; Shukuno  H.; Kawabata  H.; Ishizuka  O.; Fiske  R. S. 《Journal of Petrology》2007,48(10):1999-2031

The arc-front volcanoes of Sumisu (31·5°N, 140°E)and Torishima (30·5°N, 140·3°E) in thecentral Izu–Bonin arc are similar in size and rise asrelatively isolated edifices from the seafloor. Together theyprovide valuable along-arc information about magma generationprocesses. The volcanoes have erupted low-K basalts originatingfrom both wet and dry parental basaltic magmas (low-Zr basaltsand high-Zr basalts, respectively). Based on models involvingfluid-immobile incompatible element ratios (La/Sm), the parentalbasalts appear to result from different degrees of partial meltingof the same source mantle (20% and 10% for wet and dry basaltmagmas, respectively). Assuming that the wet basalts containgreater abundances of slab-derived components than their drycounterparts, geochemical comparison of these two basalt typespermits the identification of the specific elements involvedin fluid transport from the subducting slab. Using an extensiveset of new geochemical data from Torishima, where the top ofthe downgoing slab is about 100 km deep, we find that Cs, Pb,and Sr are variably enriched in the low-Zr basalts, which cannotbe accounted for by fractional crystallization or by differencesin the degree of mantle melting. These elements are interpretedto be selectively concentrated in slab-derived metasomatic fluids.Variations in K, high field strength element and rare earthelement concentrations are readily explained by variations inthe degree of melting between the low- and high-Zr basalts;these elements are not contained in the slab-derived fluids.Rb and Ba exhibit variable behaviour in the low-Zr basalts,ranging from immobile, similar to K, to mildly enriched in somelow-Zr basalts. We suggest that the K-rich mica, phengite, playsan important role in determining the composition of fluids releasedfrom the downgoing slab. In arc-front settings, where slab depthis 100 km, phengite is stable, and the fluids released fromthe slab contain little K. In back-arc settings, however, wherethe slab is at 100–140 km depth, phengite is unstable,and K-rich fluids are released. We conclude that cross-arc variationsin the K content of arc basalts are probably related to differingcompositions of released fluids or melts rather than the widelyheld view that such variations are controlled by the degreeof partial melting. KEY WORDS: arc volcano; degrees of melting; mantle wedge; water; wet and dry basalts  相似文献   

Coronal Mass Ejections Observed at the Total Solar Eclipse on 13 November 2012     

Yoichiro Hanaoka  Jun Nakazawa  Osamu Ohgoe  Yoshiaki Sakai  Kazuo Shiota 《Solar physics》2014,289(7):2587-2599

White-light observations of the total solar eclipse on 13 November 2012 were made at two sites, where the totality occurred 35 min apart. The structure of the corona from the solar limb to a couple of solar radii was observed with a wide dynamic range and a high signal-to-noise ratio. An ongoing coronal mass ejection (CME) and a pre-CME loop structure just before the eruption were observed in the height range between 1?–?2 R_⊙. The source region of CMEs was revealed to be in this height range, where the material and the magnetic field of CMEs were located before the eruption. This height range includes the gap between the extreme ultraviolet observations of the low corona and the spaceborne white-light observations of the high corona, but the eclipse observation shows that this height range is essential for the study of CME initiation. The eclipse observation is basically just a snapshot of CMEs, but it indicates the importance of a continuous coverage of CME observations in this height range in the future.  相似文献   

The impact of the Tokyo Metropolitan Emissions Trading Scheme on reducing greenhouse gas emissions: findings from a facility-based study     

Masayo Wakabayashi  Osamu Kimura 《Climate Policy》2018,18(8):1028-1043

This paper provides a detailed analysis of the Tokyo Metropolitan Emissions Trading Scheme (Tokyo ETS), Japan’s first emissions trading scheme with mandatory cap initiated by the government of Tokyo. Unlike trading schemes in other countries, the Tokyo ETS covers indirect emissions from the commercial sector. It is well known that a variety of market barriers impede full realization of energy efficiency opportunities, especially in the commercial sector. Experiences with the Tokyo ETS should therefore provide important lessons for the design of climate change mitigation policies, especially when targeting the commercial sector. The emissions from covered entities have been drastically reduced from those at the scheme’s outset, with an average 14% reduction as of the end of the first commitment period of five years (2010–2014) compared with 2009 levels. This paper shows that the Tokyo ETS alone did not cause these reductions; there were other drivers. Among them, the energy savings triggered by the Great East Japan Earthquake in 2011 were crucial. The contribution of credit trading, in contrast, was limited since most of the covered entities reduced emissions by themselves. Through an investigation of official reports, an assessment of the emissions data from the covered entities compared to those of uncovered entities and in-depth interviews with firms covered by the scheme, this paper confirms that the main drivers of emissions reductions by covered entities were separate from the ETS. In fact, the advisory aspect of the scheme seems to be much more important in encouraging energy-saving actions.

Key policy insights

• Most of the observed emission reductions were not caused by the Tokyo ETS alone.

• An advisory instrument was crucial to the effectiveness of the Tokyo ETS.

• The experience of the Tokyo ETS suggests that making full use of the advantages of emissions trading is difficult in the case of the commercial sector.

• Price signals have not provided a stimulus to climate change mitigation actions, which implies that establishing a cap to yield effective carbon prices poses a challenge.

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Sources and depositional processes of tsunami deposits: Analysis using foraminiferal tests and hydrodynamic verification     

Jun‐Ichi Uchida  Osamu Fujiwara  Shiro Hasegawa  Takanobu Kamataki 《Island Arc》2010,19(3):427-442

Foraminiferal tests are commonly found in tsunami deposits and provide evidence of transport of sea floor sediments, sometimes from source areas more than 100 m deep and several kilometers away. These data contribute to estimates of the physical properties of tsunami waves, such as their amplitude and period. The tractive force of tsunami waves is inversely proportional to the water depth at sediment source areas, whereas the horizontal sediment transport distance by tsunami waves is proportional to the wave period and amplitude. We derived formulas for the amplitudes and periods of tsunami waves as functions of water depth at the sediment source area and sediment transport distance based on foraminiferal assemblages in tsunami deposits. We applied these formulas to derive wave amplitudes and periods from data on tsunami deposits in previous studies. For some examples, estimated wave parameters were reasonable matches for the actual tsunamis, although other cases had improbably large values. Such inconsistencies probably reflect: (i) local amplification of tsunami waves by submarine topography, such as submarine canyons; and (ii) errors in estimated water depth at the sediment source area and sediment transport distance, which mainly derive from insufficient identification of foraminiferal tests.  相似文献